在文献中看到“γ effect ”这个概念,不知道是什么意思,有没有哪位高人指点下?
* o1 L3 p% z6 b, n原文是这样说的: a 'tentative assignment is proposed.
4 {; [. j6 p4 W) K! pSuch an assignment is based on consideration of the
# N. c. d5 i2 p' s: J) k1 s1 R“γ effect,” i.e. the steric polarization shift which
) @: a4 [1 Y0 e4 I- ~3 hhas been observed whenever a carbon is close to a
/ p2 o% n4 j; J/ `, P. }. }γ-carbon or a γ-oxygen.+ H. W, Z& V' s* ~; m; ]& O
不明白这句话的意思,steric polarization shift 指的是什么啊,望不吝赐教,谢谢! |