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Publisher: Academic Press
* b* T# R* k$ P3 Q9 ZNumber Of Pages: 249
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Publication Date: 1995-04-12
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Sales Rank: 2091040
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ISBN / ASIN: 0127309454
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EAN: 9780127309453
7 @4 V2 ^, M3 A% J- {Binding: Hardcover
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Manufacturer: Academic Press
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Studio: Academic Press
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Description:
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The book opens with a general overview of the constitution and
5 W0 ~4 J% y$ n' l b& ereactivity of organomagnesium compounds, followed by information on
* V5 {* C; _1 i& C0 Y3 Ihandling them and on their detection and estimation. Throughout,2 o+ h" | g' N
practical aspects aswell as principles are emphasized.
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The chapters on the synthesis of organomagnesium compounds cover the
" g) P* _( Y+ @* c2 O5 p1 \preparation of special forms of metallic magnesium and the reaction of% w% z* D* K$ u2 n% J
magnesium with substrates such as dienes, as well as the traditional8 c5 v; f J- k# y# J
preparation of Grignard reagents. Preparations by metallation and
; M! S. s- v1 P. i- A; ?metal-halogen exchanges are also included, as are newer methods such as; {" L1 B. j3 r4 j9 Z) L; A
hydromagnesiation of alkenes and alkynes.
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Systematic coverage is provided on synthetically useful reactions of" K+ s( _" I' A) h( |
organomagnesium compounds. Of fundamental importance in organic
* R$ H4 D9 s% {3 F v- f6 Bsynthesis are carbon-carbon bond forming reactions; additions to
3 `+ ^9 E+ L* u& N7 S ycarbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur m% M* e( |& k* r
multiple bonds; and nucleophilic substitution at carbon. The formation
8 _. {! N: R1 H* L- }" Y9 ~# Tof carbon-heteroatom bonds in organic compounds is described, where the
& w; ]- U- u7 ~ U oheteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally,1 n, U9 P' }/ I+ Q6 A k
the use of organomagnesium compounds in preparing other organometalloid6 I0 z7 Q7 {) c6 [7 G
and organometallic compounds is outlined.
6 t" h0 g# k. h* I3 e+ C* \Representative experimental procedures are included throughout the
) J% A9 d3 U& [; Hbook, and tables with references to well-described examples are* _* ^% N- O% e! z* g* |9 e9 E- X
provided.
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Key Features
+ {; S* a$ W; S# k) q* Presents a general overview of the constitution and reactivity of organomagnesium compounds
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* Provides coverage on the detection and estimation of organomagnesium compounds
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* Emphasizes practical aspects as well as principles
3 @8 ^ A) [$ Q- E* Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes
, W- X2 I; Z: } `( @% P( S! H* Includes preparations by metallation and metal-halogen exchanges
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* Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes
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* Outlines information on synthetically useful reactions of organomagnesium compounds
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* Describes the formation of carbon-heteroatom bonds in organic compounds
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* Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds
' y; _+ w" x0 \/ a* Includes representative procedures and tables with references to well-described examples
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发表于 2007-9-13 19:39:13
