氚代溶剂

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常见溶剂的¹H在不同氘代溶剂中的化学位移值

	mult.	氘 代 溶 剂
		CDCl3	(CD3)2CO	(CD3)2SO	C6D6	CD3CN	CD3OD	D2O	C5D5N
残余溶剂峰		7.26	2.05	2.50	7.16	1.94	3.31	4.79	7.20 7.57 8.72
水峰	brs	1.56	2.84	3.33	0.40	2.13	4.87	4.79	4.96
CHCl3	s	7.26	8.02	8.32	6.15	7.58	7.90
(CH3)2CO	s	2.17	2.09	2.09	1.55	2.08	2.15	2.22
(CH3)2SO	s	2.62	2.52	2.54	1.68	2.50	2.65	2.71
C6H6	s	7.36	7.36	7.37	7.15	7.37	7.33
CH3CN	s	2.10	2.05	2.07	1.55	1.96	2.03	2.06
CH3OH	CH3,s OH,s	3.49 1.09	3.31 3.12	3.16 4.01	3.07	3.28 2.16	3.34	3.34
C5H5N	CH(2),m CH(3),m CH(4),m	8.62 7.29 7.68	8.58 7.35 7.76	8.58 7.39 7.79	8.53 6.66 6.98	8.57 7.33 7.73	8.53 7.44 7.85	8.52 7.45 7.87	8.72 7.20 7.57
CH3COOC2H5	CH3,s CH2,q CH3,t	2.05 4.12 1.26	1.97 4.05 1.20	1.99 4.03 1.17	1.65 3.89 0.92	1.97 4.06 1.20	2.01 4.09 1.24	2.07 4.14 1.24
CH2Cl2	s	5.30	5.63	5.76	4.27	5.44	5.49
n-hexane	CH3,t CH2,m	0.88 1.26	0.88 1.28	0.86 1.25	0.89 1.24	0.89 1.28	0.90 1.29
C2H5OH	CH3,t CH2,q	1.25 3.72	1.12 3.57	1.06 3.44	0.96 3.34	1.12 3.54	1.19 3.60	1.17 3.65

常见溶剂的¹³C在不同氘代溶剂中的化学位移值

	氘 代 溶 剂
	CDCl3	(CD3)2CO	(CD3)2SO	C6D6	CD3CN	CD3OD	D2O	C5D5N
溶剂峰	77.16	206.26 29.84	39.52	128.06	1.32 118.26	49.00	-	123.44 135.43 149.84
CHCl3	77.36	79.19	79.16	77.79	79.17	79.44
(CH3)2CO	207.07 30.92	205.87 30.60	206.31 30.56	204.43 30.14	207.43 30.91	209.67 30.67	215.94 30.89
(CH3)2SO	40.76	41.23	40.45	40.03	41.31	40.45	39.39
C6H6	128.37	129.15	128.30	128.62	129.32	129.34
CH3CN	116.43 1.89	117.60 1.12	117.91 1.03	116.02 0.20	118.26 1.79	118.06 0.85	119.68 1.47
CH3OH	50.41	49.77	48.59	49.97	49.90	49.86	49.50
C5H5N	149.90 123.75 135.96	150.67 124.57 136.56	149.58 123.84 136.05	150.27 123.58 135.28	150.76 127.76 136.89	150.07 125.53 138.35	149.18 125.12 138.27
CH3COOC2H5	21.04 171.36 60.49 14.19	20.83 170.96 60.56 14.50	20.68 170.31 59.74 14.40	20.56 170.44 60.21 14.19	21.16 171.68 60.98 14.54	20.88 172.89 61.50 14.49	21.15 175.26 62.32 13.92
CH2Cl2	53.52	54.95	54.84	53.46	55.32	54.78
n-hexane	14.14 22.70 31.64	14.34 23.28 32.30	13.88 22.05 30.95	14.32 23.04 31.96	14.43 23.40 32.36	14.45 23.68 32.73
C2H5OH	18.41 58.28	18.89 57.72	18.51 56.07	18.72 57.86	18.80 57.96	18.40 58.26	17.47 58.05

 *更多信息请参考"J.Org. Chem. 1997,62,7512-7515"

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