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NMR Solvents
% e& C( P J& {: [# A
# T; e& \, v( O; [' t' V | Solvent | Formula | 1H shifts | 13C shifts | bp °C
+ }* @7 s9 b. g* ~ | mp °C | bp °C1 h. P& D4 }* q/ i
| | Acetic Acid-d4 | CD3COOD | 2.0, 11.7 | 20.0, 180.0 | 16.6 | 117.9 | | Acetone-d6 | CD3COCD3 | 2.09 | 29.9, 206.7 | -94.7 | 56.1 | | Acetonitrile-d3 | CD3CN | 1.94 | 1.4, 118.7 | -43.8 | 81.6 | | Benzene-d6 | C6D62 r: |( h( J: r1 p3 Y) O' ]
| 7.16 | 128.4 | 5.5 | 80.1 | | Carbon Disulphide | CS2 | none | 192.8 | -11.6 | 46.3 | | Carbon Tetrachloride | CCl4 | none | 96.7 | -23.0 | 76.8 | | Chloroform-d | CDCl33 j4 ~4 R5 b7 U9 W# v6 G% `
| 7.24 | 77.23 | -63.5 | 61.3 | | Dichloromethane-d2 | CD2Cl2
7 X5 b* x( c0 v- | | 5.32 | 54.0 | -95.1 | 40.8 | | Diethyl Ether (-100 °C) | (CH3CH2)2O | | ?, 66.51 | -116.3 | 34.6 | | Dimethyl Ether (-100 °C) | CH3OCH3+ W5 m& i' z/ J" E! @. H% T
| 3.2 | 60.08 | -138.5 | -23 | | N,N-Dimethyl formamide-d7 | Me2NCHO | 2.95, 2.75, 8.03 | 29.8, 34.9, 163.2 | -61.? | 153.? | | Dimethyl Sulfoxide-d6; |' G0 q" N3 s2 R4 P
| CD3SOCD3
. Q4 `" p$ P6 X3 Q) ] | 2.50 | 39.5 | 18.6 | 189.0 | |
| 1,4-Dioxan | (OCH2CH2)2 | 3.53 | 66.7 | 11.8 | 101.4 | | Ethanol-d6& G. V0 r/ k7 Y- x* {
| CD3CD2OD | 1.11, 3.56, 5.19 | 17.3, 57.0 | -117 | 78.3 | | Methanol-d4
; ^: D7 y L" N( a | CD3OD | 3.31, 4.78 | 49.2 | -97.8 | 64.6 | | Nitrobenzene | C6D5NO2% y* H$ B7 I7 G# v2 l: z( L/ e3 h# O
| 7.5, 7.7, 8.1 | 123, 129, 135 | 5.7 | 210.8 | | Nitromethane-d3
8 m/ O# [; b8 i7 a; R) J. T, m | CD3NO2
& _2 t% v" l! C+ c | 4.3 | 57.3 | -28.6 | 101.2 | | Pyridine-d5
8 I) _! F# W- y. ]. T1 \3 I | C5D5N | 7.22, 7.58, 8.74 | 123.9, 135.9, 150.2 | -41.6 | 115.3 | | 1,1,2,2-Tetrachloroethane | CHCl2CHCl2
# w$ g( @- l8 w: X; u. C | ? | 75.5 | -43.8 | 146.3 | | Tetrahydrofuran-d8& c9 G* k! J4 V. m F/ R) ~
| C4D8O | 1.73, 3.58 | 25.4, 67.6 | -108.5 | 65.4 | | Tetrahydrofuran -100 °C | C4H8O | | ?, 67.96 | | | | Toluene-d8
# F/ k% P% F+ j8 U8 e | C6D5CD3
- X( l/ x! P$ J5 V) X6 J | 2.09, 6.98, 7.00, 7.09 | 20.4, 125.5, 128.3, 129.4, 137.9 | -94.9 | 110.6 | | Trichlorofluoromethane | CFCl3% a" }" r+ K7 \
| none | 117.6 | -111 | 23.7 | | Trifluoroacetic Acid-d4# u7 G: w+ u# M2 x! {) B0 j
| CF3COOD | 11.5 | 116.6, 164.2 | -15.3 | 72.4 | | Trifluoroethanol-d3% m0 `0 R E4 h l
| CF3CD2OD | 3.88, 5.02 | 61.5, 126.3 | -15.3 | 72.4 | | Water | D2O | 4.8 | none | 0.0 | 100.0 | | Solvent | Formula | 1H shifts | 13C shifts | bp °C 8 ^5 _# _. t& y( L+ S5 w
| mp °C | bp °C | |
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发表于 2007-1-23 15:53:48
