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Publisher: Academic Press
4 I% I0 I: N! d0 ?3 BNumber Of Pages: 249
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Publication Date: 1995-04-12
* G: N' O7 N( Y0 L+ B# Z+ ZSales Rank: 2091040
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ISBN / ASIN: 0127309454
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EAN: 9780127309453
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Binding: Hardcover
( V% e, t" _% ^" P8 e; e: e7 BManufacturer: Academic Press
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Studio: Academic Press
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Description:
+ g5 m3 ]$ ]" t- I+ U* i( GThe book opens with a general overview of the constitution and: b4 }5 L# O1 @, N% C/ F- I& u3 k
reactivity of organomagnesium compounds, followed by information on
4 k/ _6 b/ \$ ]$ ^5 Chandling them and on their detection and estimation. Throughout,
) R+ m" ^, C! M: O" k. l0 wpractical aspects aswell as principles are emphasized.
- ~) M* s& D( F' kThe chapters on the synthesis of organomagnesium compounds cover the
# b- l" L, A5 c1 x* npreparation of special forms of metallic magnesium and the reaction of# Q' {0 s# _: e H
magnesium with substrates such as dienes, as well as the traditional* u$ L, H# \) t/ K2 k* R
preparation of Grignard reagents. Preparations by metallation and2 m) Y- ]6 k0 B# B. h
metal-halogen exchanges are also included, as are newer methods such as
7 F! h3 ^2 r& R& Shydromagnesiation of alkenes and alkynes.
: d) m9 a. n+ t( ` uSystematic coverage is provided on synthetically useful reactions of
+ z4 x; d$ _$ v, a4 T. h eorganomagnesium compounds. Of fundamental importance in organic; m4 t0 n& ]8 M5 V- ^0 G" h+ x
synthesis are carbon-carbon bond forming reactions; additions to
8 }& o, I" j; k% Rcarbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur5 M9 g3 d0 g3 d) y# J g; @. L6 J( j
multiple bonds; and nucleophilic substitution at carbon. The formation
1 F/ n3 f1 K% R5 L/ Mof carbon-heteroatom bonds in organic compounds is described, where the
# \# y/ @& [; gheteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally,1 S7 u& ~, D- a
the use of organomagnesium compounds in preparing other organometalloid
0 l. W! `& k4 nand organometallic compounds is outlined.
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Representative experimental procedures are included throughout the; \ ^+ c2 u, G. z* Y6 z; b5 I
book, and tables with references to well-described examples are
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Key Features
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* Presents a general overview of the constitution and reactivity of organomagnesium compounds
) Q7 E) e- p# u- i# H, B* Provides coverage on the detection and estimation of organomagnesium compounds
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* Emphasizes practical aspects as well as principles
- j0 q: r1 t2 T p6 T8 e* Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes
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* Includes preparations by metallation and metal-halogen exchanges
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* Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes
+ ?: n) D' I6 T& o6 ~* Outlines information on synthetically useful reactions of organomagnesium compounds
, S4 [; y' E1 t& H! f |2 R* Describes the formation of carbon-heteroatom bonds in organic compounds
- g2 `8 L0 y! A; ]3 C# a' f. V; O* Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds
9 b$ |$ J& ^$ v8 M$ m9 ]* Includes representative procedures and tables with references to well-described examples
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发表于 2007-9-13 19:39:13
