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Publisher: Academic Press
5 X5 e, p T8 a% [- INumber Of Pages: 249
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Publication Date: 1995-04-12
( C, _( L/ @% i# f6 x4 b- QSales Rank: 2091040
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ISBN / ASIN: 0127309454
7 c: w- T( m y# zEAN: 9780127309453
, Y/ q. C1 U, @' u* lBinding: Hardcover
0 ^4 \" H# h: B& nManufacturer: Academic Press
, m* d* f7 Q0 \( d8 G) N7 zStudio: Academic Press
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8 A! r! T: O, Q8 i3 d9 s* k7 pDescription:
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The book opens with a general overview of the constitution and4 J# N* V& g4 q* x! b6 l
reactivity of organomagnesium compounds, followed by information on3 n$ P1 S- p. `4 p, d2 m
handling them and on their detection and estimation. Throughout,
w/ I* [+ n) Hpractical aspects aswell as principles are emphasized.
% F7 E+ H* a$ d, UThe chapters on the synthesis of organomagnesium compounds cover the5 p: r& f( e) }& X4 L
preparation of special forms of metallic magnesium and the reaction of
) p2 ?9 R4 ?0 j. {: g0 N6 }magnesium with substrates such as dienes, as well as the traditional' R; ~/ f) @& V) F! _ Y
preparation of Grignard reagents. Preparations by metallation and
& ]8 @5 j$ g) vmetal-halogen exchanges are also included, as are newer methods such as
. p' o* l9 Z4 w" chydromagnesiation of alkenes and alkynes.
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Systematic coverage is provided on synthetically useful reactions of
: Z* R6 X3 R, ?- eorganomagnesium compounds. Of fundamental importance in organic _) K f# z- }2 |( ~0 C
synthesis are carbon-carbon bond forming reactions; additions to+ ~) y7 |8 W {! @1 m7 }8 a
carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur# H; m/ e2 e5 j6 |; `5 U/ i% {; A
multiple bonds; and nucleophilic substitution at carbon. The formation
+ e8 }; \% b- o1 ?+ Tof carbon-heteroatom bonds in organic compounds is described, where the
* {7 j/ d7 k3 i' T, i8 Zheteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally,- V) `2 W7 [8 _- t
the use of organomagnesium compounds in preparing other organometalloid. k/ N; n6 B7 u6 i- N8 r6 C1 H
and organometallic compounds is outlined.
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Representative experimental procedures are included throughout the/ t: e* g7 \$ G
book, and tables with references to well-described examples are% ^0 m8 e( {' o y {
provided.
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Key Features
. x! b2 t: r( {! q+ U0 Q* Presents a general overview of the constitution and reactivity of organomagnesium compounds
, T% \6 L6 r' A a$ M# B* Provides coverage on the detection and estimation of organomagnesium compounds
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* Emphasizes practical aspects as well as principles
9 F. v/ h3 Z* `2 N1 x; z* Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes
* Z! D4 w9 t. L, M) } l* Includes preparations by metallation and metal-halogen exchanges
- w( L+ q5 C; h* Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes
2 i; P' k; b2 B* Outlines information on synthetically useful reactions of organomagnesium compounds
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* Describes the formation of carbon-heteroatom bonds in organic compounds
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* Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds
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* Includes representative procedures and tables with references to well-described examples
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发表于 2007-9-13 19:39:13
