[下载]Exercises in Synthetic Organic Chemistry

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[Money=100]Contents
List of Abbreviations xiii
Introduction 1
1. Total Synthesis of (-)-Ovatolide 3
2. Total Synthesis of RS-15385 4
3. Total Synthesis of Islandic Acid I Methyl Ester 5
4. Total Synthesis of (+)-PatulolideC 6
5. Asymmetric Synthesis of l-Deoxy-8,8a-di-epi-castanospermine 8
6. Synthesis of a Structure Related to Hydantocidin 9
7. Total Synthesis of Cryptophycin C 10
8. Total Synthesis of (±)-Leuhistin 12
9. The Asymmetric Synthesis of Bryostatin Fragments 13
10. The Total Synthesis of (-)-Balanol 14
11. Approach to the Synthesis of Pseudopterosins 16
12. Total Synthesis of Neodolabellenol 17
13. Total Synthesis of (-)-Swainsonine 18
14. Total Synthesis of Octalactins A and B 19
15. Asymmetric Synthesis of the Milbemycin B3 Spiroketal Subunit 20
16. Stereoselective Total Synthesis of (+)-Artemisinin 22
17. The Synthesis of (±)-Prosopinine 24
18. Synthesis of a Protected Fluorocarbocyclic Nucleoside 25
19. Synthesis of Tropane Alkaloid Calystegine A3 26
20. The Synthesis of (±)-Oxerine 28
21. Synthesis of an Enantiopure C-4 Functionalised 2-Iodocyclohexanone Acetal 29
22. Total Synthesis of (-)-Solavetivone 30
23. Total Synthesis of (+)-Himbacine 32
24. Synthesis of 5-Hydroxytiagabine 34
25. An Approach to Zoanthamine Alkaloids 35
26. Total Synthesis of 1233A 36
27. Synthesis of a Key Intermediate of 13-Methylcarbapenem Antibiotics 38
28. Total Synthesis of the Enantiomer of Hennoxazole A 40
29. Total Synthesis of (+)-Duocarmycin A 41
30. Studies Towards the Total Synthesis of Rapamycin 42
31. Studies Towards the Total Synthesis of Rapamycin 44
32. Studies Towards the Total Synthesis of Rapamycin 46
33. Synthesis of Isochromanquinones 47
34. The Synthesis of (±)-12a-Deoxytetracycline 48
35. Synthesis of a D-c/z/ro-Inositol 1 -Phosphate 50
36. Stereoselective Synthesis of (±)-Aromaticin 51
37. Synthesis of 7-Methoxycyclopropamitosene 52
38. Total Synthesis of (+)-y-Lycorane 53
39. Enantioselective Total Synthesis of (-)-7-Deacetoxyalcyonin Acetate 54
40. Total Synthesis of (+)-Tetrahydrocerulenin 56
41. Total Synthesis of (+)-Longifolene 57
42. Studies toward the Total Synthesis of Cerorubenic Acid-Ill 58
43. Total Synthesis of 10-Decarboxyquinocarcin 60
44. Total Synthesis of (+)-Pyripyropene A 62
45. Total Synthesis of d,/-Isospongiadiol 63
46. Total Synthesis of the Stemona Alkaloid (-)-Stenine 64
47. Total Synthesis of (-)-Papuamine 65
48. Total Synthesis of (+)-Stoechospermol 66
49. Synthesis of the Tricarbonyl Subunit C8-C19 of Rapamycin 68
50. Synthesis of the AB Ring Moiety of Ciguatoxin 70
51. Total Synthesis of (+)-Carbonolide B 72
52. Approach Towards the Asteriscanolide Skeleton 74
53. Total Synthesis of (+)-Dolabellatrienone 75
54. Total Synthesis of Stenine 76
55. Synthesis of 3B-Acetoxydrimenin 78
56. The Total Synthesis of (+)-Adrenosterone 79
57. Total Synthesis of (-)-Suaveoline 80
58. Total Synthesis of (+)-7-Deoxypancratistatin 82
59. Enantioselective Synthesis of Deoxynojirimycin 84
60. Formal Synthesis of (±)-Aphidicolin 85
61. Synthetic Efforts Towards Bruceantin 86
62. Total Synthesis of (+)-FR900482 88
63. Total Synthesis of (3Z)-Dactomelyne 90
64. Total Synthesis of (±)-Acerosolide 92
65. Synthesis of a Vindorosine Precursor 93
66. Synthesis of (-)-PGE2 Methyl Ester 94
67. Total Synthesis of (-)-Parviflorin 96
68. Total Synthesis of (-)-Chlorothricolide 98
69. Synthetic Studies on Furanoheliangolides 100
70. Total Synthesis of Staurosporine 102
71. Total Synthesis of (-)-Cephalotaxine 104
72. The Synthesis of Picrotoxinin 106
73. Total Synthesis of (+)-Dactylol 107
74. Synthesis of (±)-Ceratopicanol 108
75. Total Synthesis of (±)-MyrocinC 110
76. Synthesis of Staurosporine Aglycon 112
77. Synthesis of (205)-Camptothecin 113
78. Synthesis of a Fragment of (+)-Codaphniphylline 114
79. The Total Synthesis of Indanomycin 116
80. A Total Synthesis of Taxol 118
81. Total Synthesis of (-)-Grayanotoxin III 120
82. Enantioselective Total Synthesis of (-)-Strychnine 122


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