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NMR Solvents
5 d, W3 e/ `9 U/ ]) T. w
) U0 C. p. |. p+ O, I. d. V | Solvent | Formula | 1H shifts | 13C shifts | bp °C
3 w% x% k z& _6 ^9 ^, F | mp °C | bp °C2 c- n/ a2 _( ~, q
| | Acetic Acid-d4 | CD3COOD | 2.0, 11.7 | 20.0, 180.0 | 16.6 | 117.9 | | Acetone-d6 | CD3COCD3 | 2.09 | 29.9, 206.7 | -94.7 | 56.1 | | Acetonitrile-d3 | CD3CN | 1.94 | 1.4, 118.7 | -43.8 | 81.6 | | Benzene-d6 | C6D67 W6 Z9 R4 a' E, k
| 7.16 | 128.4 | 5.5 | 80.1 | | Carbon Disulphide | CS2 | none | 192.8 | -11.6 | 46.3 | | Carbon Tetrachloride | CCl4 | none | 96.7 | -23.0 | 76.8 | | Chloroform-d | CDCl3& t$ Q2 |4 o$ f) F; m
| 7.24 | 77.23 | -63.5 | 61.3 | | Dichloromethane-d2 | CD2Cl2* I. i1 o5 D2 g* [" h
| 5.32 | 54.0 | -95.1 | 40.8 | | Diethyl Ether (-100 °C) | (CH3CH2)2O | | ?, 66.51 | -116.3 | 34.6 | | Dimethyl Ether (-100 °C) | CH3OCH3
% ^& w% m$ g2 Q/ T$ R' t | 3.2 | 60.08 | -138.5 | -23 | | N,N-Dimethyl formamide-d7 | Me2NCHO | 2.95, 2.75, 8.03 | 29.8, 34.9, 163.2 | -61.? | 153.? | | Dimethyl Sulfoxide-d6' [1 a" ^, P; I! y, _
| CD3SOCD3
0 u$ @. c/ s8 l0 v3 W6 ~ | 2.50 | 39.5 | 18.6 | 189.0 | |
| 1,4-Dioxan | (OCH2CH2)2 | 3.53 | 66.7 | 11.8 | 101.4 | | Ethanol-d68 q1 {6 r0 J. ?" U% _
| CD3CD2OD | 1.11, 3.56, 5.19 | 17.3, 57.0 | -117 | 78.3 | | Methanol-d4
/ z$ Z; N* s% e | CD3OD | 3.31, 4.78 | 49.2 | -97.8 | 64.6 | | Nitrobenzene | C6D5NO2
. j& w5 `, z3 g+ V$ G( J | 7.5, 7.7, 8.1 | 123, 129, 135 | 5.7 | 210.8 | | Nitromethane-d3; c: p: ~% K" F+ S
| CD3NO2
( v6 q, l! Q* ]# O& H' | | 4.3 | 57.3 | -28.6 | 101.2 | | Pyridine-d5- H# y& p% e, X$ ^
| C5D5N | 7.22, 7.58, 8.74 | 123.9, 135.9, 150.2 | -41.6 | 115.3 | | 1,1,2,2-Tetrachloroethane | CHCl2CHCl2' h5 x0 `4 u; W z' m
| ? | 75.5 | -43.8 | 146.3 | | Tetrahydrofuran-d8 s7 h1 E( Z7 E& R4 y$ I, [. F
| C4D8O | 1.73, 3.58 | 25.4, 67.6 | -108.5 | 65.4 | | Tetrahydrofuran -100 °C | C4H8O | | ?, 67.96 | | | | Toluene-d8
8 ]) g" g' T) T | C6D5CD31 K: q, b; ~7 \
| 2.09, 6.98, 7.00, 7.09 | 20.4, 125.5, 128.3, 129.4, 137.9 | -94.9 | 110.6 | | Trichlorofluoromethane | CFCl3
& b; e$ p( E* C' K+ \6 s1 F | none | 117.6 | -111 | 23.7 | | Trifluoroacetic Acid-d4
5 Q; K8 E, D9 x | CF3COOD | 11.5 | 116.6, 164.2 | -15.3 | 72.4 | | Trifluoroethanol-d36 a& a6 Z# H- ?4 p0 R
| CF3CD2OD | 3.88, 5.02 | 61.5, 126.3 | -15.3 | 72.4 | | Water | D2O | 4.8 | none | 0.0 | 100.0 | | Solvent | Formula | 1H shifts | 13C shifts | bp °C
0 o# K) Z1 w& g6 h7 w | mp °C | bp °C | |
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发表于 2007-1-23 15:53:48
