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在文献中看到“γ effect ”这个概念,不知道是什么意思,有没有哪位高人指点下?9 S: ^1 P+ B* R; u
原文是这样说的: a 'tentative assignment is proposed.
D! O- T; {$ j+ I8 E: y, q. \Such an assignment is based on consideration of the
; h/ Q9 q- I9 [0 `“γ effect,” i.e. the steric polarization shift which
8 n+ r7 b( j. F2 {has been observed whenever a carbon is close to a# F# y' P, T) a
γ-carbon or a γ-oxygen.
* B4 z$ ~5 \0 g/ t不明白这句话的意思,steric polarization shift 指的是什么啊,望不吝赐教,谢谢! |