在文献中看到“γ effect ”这个概念,不知道是什么意思,有没有哪位高人指点下?* H) e+ x8 X# b( g8 J3 F% a7 x
原文是这样说的: a 'tentative assignment is proposed.
2 [& K2 u% Y8 j; B4 HSuch an assignment is based on consideration of the. ] _4 w2 j/ j' w3 n
“γ effect,” i.e. the steric polarization shift which
& Y* }4 E9 \! g, c( @1 q* ~has been observed whenever a carbon is close to a# U) i' g' A3 t9 @
γ-carbon or a γ-oxygen.5 X+ X! q* T- c$ M1 q
不明白这句话的意思,steric polarization shift 指的是什么啊,望不吝赐教,谢谢! |