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Publisher: Academic Press
* P6 R) K6 }5 W6 x( ~Number Of Pages: 249
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Publication Date: 1995-04-12
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Sales Rank: 2091040
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ISBN / ASIN: 0127309454
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EAN: 9780127309453
1 f, H' x r" z0 w% W8 BBinding: Hardcover
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Manufacturer: Academic Press
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Studio: Academic Press
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; I, Q& y+ l9 X( d8 ]Description:
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The book opens with a general overview of the constitution and
) d, S) {: C! K o" `reactivity of organomagnesium compounds, followed by information on
1 D, ] q5 x+ \$ M7 ]handling them and on their detection and estimation. Throughout,9 `7 d+ i9 O9 Z, E; \5 L! t
practical aspects aswell as principles are emphasized.
+ O9 i3 N: W& g4 f0 jThe chapters on the synthesis of organomagnesium compounds cover the
9 F& [3 J2 \; k- T+ u8 Cpreparation of special forms of metallic magnesium and the reaction of% p" ]& V7 D5 T0 M) u, T3 G
magnesium with substrates such as dienes, as well as the traditional
& d* N7 P0 o \8 jpreparation of Grignard reagents. Preparations by metallation and
* j" f, v$ n* F8 r, |metal-halogen exchanges are also included, as are newer methods such as* x2 x2 ]( x6 ~% q6 `
hydromagnesiation of alkenes and alkynes.
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Systematic coverage is provided on synthetically useful reactions of; A- }, q0 ?8 l- V$ }" G9 Q
organomagnesium compounds. Of fundamental importance in organic" F% R+ B2 r: x8 d
synthesis are carbon-carbon bond forming reactions; additions to' N4 R) ^( k i/ g: w e
carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur$ L# w- _! b$ G. h: ?! e. P
multiple bonds; and nucleophilic substitution at carbon. The formation v8 b( Y# W7 `* W0 B: p" w Y
of carbon-heteroatom bonds in organic compounds is described, where the
: O+ o3 M& l1 x; Yheteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally, o; ]/ B6 ]* P: l! k
the use of organomagnesium compounds in preparing other organometalloid2 u3 o1 z$ g: E7 S* _8 o" m! I
and organometallic compounds is outlined.
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Representative experimental procedures are included throughout the6 L& l7 h" X0 D) ]" @
book, and tables with references to well-described examples are& U+ `# ^( a- D: \; H$ N
provided.
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( y3 j; m) p; x+ L( s" Q6 K* IKey Features
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* Presents a general overview of the constitution and reactivity of organomagnesium compounds
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* Provides coverage on the detection and estimation of organomagnesium compounds
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* Emphasizes practical aspects as well as principles
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* Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes
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* Includes preparations by metallation and metal-halogen exchanges
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* Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes
6 ?( s8 v% E6 Q$ m+ ?$ o# S* Outlines information on synthetically useful reactions of organomagnesium compounds
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* Describes the formation of carbon-heteroatom bonds in organic compounds
) g4 o7 K) {$ ~# X0 X f0 `* Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds
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* Includes representative procedures and tables with references to well-described examples
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发表于 2007-9-13 19:39:13
