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Publisher: Academic Press
+ k7 A) t1 d6 b6 I/ ?9 \- |8 aNumber Of Pages: 249
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Publication Date: 1995-04-12
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Sales Rank: 2091040
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ISBN / ASIN: 0127309454
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EAN: 9780127309453
; t8 r" Y. f* Q6 S1 j% lBinding: Hardcover
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Manufacturer: Academic Press
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Studio: Academic Press
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4 b1 K2 V; z6 ^Description:
6 t! P) R0 m% H: G# L" K% t yThe book opens with a general overview of the constitution and: v3 i2 ^- P7 v I2 j y
reactivity of organomagnesium compounds, followed by information on4 d% w* c& w$ I4 @) U) b- e4 p' D& ?
handling them and on their detection and estimation. Throughout,
6 I! S7 @: z. B6 ]( S" j! a+ t& @practical aspects aswell as principles are emphasized.
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The chapters on the synthesis of organomagnesium compounds cover the. E4 _% ^4 o: j
preparation of special forms of metallic magnesium and the reaction of
9 T: i' ? P2 A4 r9 q0 C2 X/ d% `magnesium with substrates such as dienes, as well as the traditional3 a1 L( g. }9 J s" |
preparation of Grignard reagents. Preparations by metallation and
% Z( |* g: _0 u G+ Q# ~; ^, n/ r' Dmetal-halogen exchanges are also included, as are newer methods such as
$ m8 Y. F2 E. ihydromagnesiation of alkenes and alkynes.
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Systematic coverage is provided on synthetically useful reactions of# j$ y& ?; D7 A
organomagnesium compounds. Of fundamental importance in organic
# m; b, r- U5 ?. Q7 }& l( Qsynthesis are carbon-carbon bond forming reactions; additions to U( G% O0 M0 i P5 d/ s/ f
carbon-carbon, carbon-nitrogen, carbon-oxygen, and carbon-sulfur7 g2 [8 v+ F9 j6 O
multiple bonds; and nucleophilic substitution at carbon. The formation
# f ]$ m4 `7 h" mof carbon-heteroatom bonds in organic compounds is described, where the/ u, f) U2 [5 W b2 D/ [5 e
heteroatom is hydrogen, nitrogen, oxygen, sulfur, or halogen. Finally,7 l5 v' X- i5 b( u: x. \
the use of organomagnesium compounds in preparing other organometalloid
) o2 I4 K/ @4 L' O- Z7 ^and organometallic compounds is outlined.
g4 f* N. c) Y$ k6 J# h) S) Z0 WRepresentative experimental procedures are included throughout the" m# Z$ O5 \" q( n6 u7 x
book, and tables with references to well-described examples are2 @) Q; v3 ~: `4 \
provided.
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Key Features
S1 Z# |# E2 d$ B4 X7 l5 [* Presents a general overview of the constitution and reactivity of organomagnesium compounds
$ Z" Q0 s9 D" Y( g3 Z% T/ i, P* Provides coverage on the detection and estimation of organomagnesium compounds
/ g+ K) v6 B0 A3 s5 M* Emphasizes practical aspects as well as principles
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* Covers the preparation of special forms of metallic magnesium and the reaction of magnesium with substrates such as dienes
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* Includes preparations by metallation and metal-halogen exchanges
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* Reviews new preparation methods such as hydromagnesiation of alkenes and alkynes
* V) ]6 z5 {! m" r1 `$ E* Outlines information on synthetically useful reactions of organomagnesium compounds
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* Describes the formation of carbon-heteroatom bonds in organic compounds
+ W$ U4 z7 e4 k4 S4 x; f2 s. r* Addresses the use of organomagnesium compounds in preparing other organometalloid and organometallic compounds
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* Includes representative procedures and tables with references to well-described examples
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发表于 2007-9-13 19:39:13
